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AFAIK, the first vac-forms appeared in the very early '70s. I remember Rareplanes first (a Seversky P-35) appearing about that time - 1971 would be about right. Airmodels started producing at about the same time (I remember their Go229 coming out then too).
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Etched brass was around at about the same time but only ship modelers and the railway crowd latched on to it immediately. Harry Woodman was an early exponent but mostly we aircraft modelers were a bit slow on the uptake and it's the nineties before it's in anything like widespread use.
I first saw resin moulding demonstrated, also in the early seventies, by a dental technician who was a keen WWI modeler. All his models were beautiful, but a hidious shade of pink prior to painting. Resin was used in kraft kits (chess sets etc) for quite a long time before the cottage industry movement opened up the commercial possibilities. I saw a commercial resin kit for the first time at the Model Egineer Exhibition, Wembley '82. The railway crowd again. Ifirst started playing with resin in '88 and there were already aircraft kits available by then, but mostly coversion parts. In '95, when I produced some resin kits myself, it was still just possible to get away with hand poured quality. But things changed rapidly and I certainly couldn't match the quality we see these days. *