Well, I'm greatly relieved that someone was willing to comment on the "idea". Let's see if I can spread some understanding of the possibilities and the limitations.
Jan, you have brought the most cogent questions, I'll try to address them as best I can.
The orthochromatic color response curve starts off as relatively linear in the violet-blue end of the spectrum and continues at that approximate level until the knee at the green-yellow part of the spectrum and then rapidly drops off in the yellow part and is essentially gone by the time we get to orange. Anything further to the right is not seen by orthochromatic film except as a dark surface. The area I expect the proposed concept to yield some color information is in the non-linear part of the curve around yellow, and (by elimination) red
Points to the left of the knee should be analyzed by conventional gray level analysis. Points to the right of the knee may yield information from sunlight/shadow analysis. Points beyond the film color response would be categorized as reds.
As you see, I am strictly talking wavelengths and not perceived colors. I think you will also see that yellows are not likely be be saturated on orthochromatic photographs since the bluer colors will saturate long before the yellows. Reds will never saturate.
The analysis I envision will primarily use a single photograph and you would compare brightness of a shadowed area against a homogeneous adjacent sunlit area and get a light to dark "ratio". The normalization criteria might be as simple as ensuring the rest of the photo was properly exposed. You would be looking for areas that show relatively low absolute brightening in sunlight compared to shadow.

The results could be hidden if there is a bluish "tone" mixed with the color, In that case you would probably get a relatively high brightening effect.

Jan can you see the possibilities? I appreciate the time you took to respond.
Dan-San, If it helps other members of the forum understand the subject of orthochromatic color response better, it's worth the effort. I'm glad you found it useful.
Sreiko, When I was doing preliminary investigation of this idea, I found the thread you had written earlier and considered it helpful. Thanks for your work.